52100 is all about the carbide, when you have at least .3% extra carbon you dont have much choice. If you want to maximize the stuff you need to pay attention to those carbides. In this area your heat treatments before hardening will be at least as important as your final heat and quench. In normalizing you want to go hot and put all of that carbide into solution and then cool quick enough not to have it go out of solution in a coarse form and certainly not in the grain boundaries. So the vermiculite, wood ash or leaving in the cooling forge is out of the question. Also be certain to get it hot the first time and then air cool quickly, in normalizing. Reheat a couple more times going cooler as you go. The best phases to go to the final heat treat with would be upper bainite, very fine pearlite or very fine spheroids with martensite as a last resort. Coarse pearlite or large spheroidal carbides would not be desirable.
If you do things correctly you can leave the extra carbide very finely dispersed throughout the matrix to give very good abrasion resistance with no embrittlement problems. On heating for the quench the high end will put much of those fine carbides back into solution and, as mete pointed out, result in retained austenite. I have done soak temperature experiments that show Rockwell hardness climbing steadily with every 20F less from the upper range until you drop below 1475F and then undersoaking occurs. I have managed to get 67HRC from 52100 but the strain and embrittlement becomes a problem.
If you manage to put around .7%- .8% carbon into solution for the quench and leave the rest as very fine carbide, you will achieve maximum hardness with excellent abrasion resistance and little embrittlement, but this will be determined mostly by your prior treatments. Very little can be done with carbides in the final heat if they were not ideal before. With the alloying present you can also increase this effect a bit with tempering as secondary carbides are formed. It is this factor that is responsible for all the unorthodox things that many smiths come up with for this steel, which really ammount to so many forms of what I call "carbide games".