I’m sorry you got scammed man. Pro tip: Use a credit card to pay friends and family. You have the protection of doing a chargeback through the credit card.
Has anyone actually tried/done this?
If you were using a CC to make a PayPal G&S payment, then yes, that would be a recourse (although you would most likely lose your PayPal account from doing so).
I've actually used the 'threat' of doing so, to force PayPal to issue the refund (eBay scammer, who used a scammed tracking number. No idea how they do this, but the scammers obtain an actual tracking number for a package being shipped to the buyer's city/zip code. eBay/PayPal says, "We see that the seller provided a valid tracking number, showing that the package was delivered. Tough shit").
I showed them the tracking info, including the package info (which showed 5lbs, for an item which should have weighed 60lbs), the contact email with the shipping company that stated in the reply, "I'm afraid we cannot disclose the address to which the item with this tracking number was delivered, but I can confirm that it was NOT delivered to your address that you provided in your email". Then told PayPal, "Either you issue the refund when YOUR link clearly states that the Buyer is protected, or I'll have my CC do a chargeback, then close my PayPal account". Refund was issued promptly.
But in the case of a F&F transaction, PayPal will (rightfully so) tell you, "F&F is a convenience provided by PayPal for sending funds to your Friends & Family. Unlike payments for Goods & Services, refunds are not eligible for F&F transactions".
Then what do you report to your CC issuer? "Hey, I used my CC for a PayPal F&F transaction, to circumvent tax laws, and the 3% PayPal charge for G&S payments, but the seller didn't ship my item. I want to do a chargeback"?
As Blues mentioned, using F&F carries risks, that the Buyer is knowingly undertaking.