Sweet Clover? Melilotus officinalis?
If so, the compound would be dicumarol, a powerful anticoagulant from which the more potent Warfarin rodenticide was developed. Warfarin is used now medicinally in humans I believe because it is a better anticoagulant.
Ding, ding, ding. Correct on both counts.
Just because it's interesting, the rest of the quote:
"A serious outbreak of bleeding disease in cattle occurred in many states in 1921 and, after a while, it became clear that sweetclover hay which had been subjected to unusually moist conditions and had molded, even slightly, was reponsible. The haying season of 1921 was exceptionally moist and more sweetclover hay molded than usual.
Molded sweetclover hay somehow reduces the amount of one of the factors needed in the blood for clotting and thus prevents clots from forming. As in bracken poisoning, small cuts or scratches in the walls of the digestive system bleed uncontrollably. Muscle bruises bleed internally and large masses of blood collect beneath the skin. These appear as raised areas on the surface of the body, sometimes becoming several feet in circumference and as much as a foot high. Animals literally bleed to death in their own tissues and large quantities of blood may also be found in the intestines after death. Clotting power decreases steadily over several days or longer, during which animals appear perfectly healthy. But if minor operations such as dehorning are performed on animals in early stages of sweetclover poisoning, bleeding often cannot be stopped and many animals have died in this way.
A lot of people were involved in the hunt for the toxic compound in sweetclover. Toxicity was first associated with the presence in the plant of a bitter compound called coumarin. An ingenious experiment was performed from which it became obvious that under conditions of moisture that lead to mold, two molecules of coumarin combine chemically to form a single molecule of a new substance called dicoumarin. Dicoumarin was then found to be an effective anticoagulant for use in human medicine. This was the principal medicine employed, for example, when President Eisenhower suffered a heart attack while in office.
Dicoumarin has also been very successful as a rodenticide. Rodents are more susceptible to it than are other animals, so that quantities effective in killing rats are not likely to be sufficient to kill other types of animals. The rodenticide is called "Warfarin" after the initial letters of Wisconsin Alumni Research Foundation, the research laboratory which developed it. One never knows what path will open when new research projects are undertaken. This project, designed originally to learn about the causes and hopefully the control of a disease of cattle, led surprisingly to the discovery of one of man's more useful medicines, to a very effective agricultural chemical, and to excellent financial support for the Wisconsin Alumni Research Foundation." (Deadly Harvest, John M. Kingsbury, Holt Paperback, Holt Rinehart & Winston, 1972, ISBN# 0-03-091479-5, page 92)
BTW, there's also a White Sweetclover (Melilotus alba)
You're up, rk.
Doc