Glue Wars 2

Another "sticky" thread I've really enjoyed.
Glad you guys have gone through all this trouble to do some testing, as all the manufacturers would lead you to believe their products are the end all - be all in adhesives.
Thanks,
Howie
 
Howie,

You're most welcome. Glad you're enjoying the war :) Also, thanks for your input. Most helpful.

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OK Report on testbar 3 - The thin glue line test.

To get everything up to date......

This time the bar was ground clean with a 50grit. Then sandblasted with real sand. Wiped off with a paper towel (no solvents).

The attachment method was C-clamping with moderate pressure.

-------------------------------------------------------
After a few days cure:

Impact test (heretoforwards known as "Wack")
Wack
JB Weld - Failed
Wack
Dishwasher
Freeze one hour -
West Systems - Failed
Freeze eight hours
Wack
Wack
Acraglas Gel - Failed
Wack

Still in there:

Loctite Xtreme (some kinda rubberized super glue)
Loctite 406 (commercial super glue)
Loctite E-120HP
Loctite U05-FL
Gorilla Glue

Steve
 
fitzo said:
Perhaps this has already been addressed and I missed it in my fog:

While reading about Gorilla Glue on their website, I noticed that they recommended "something other than poly adhesives" if one is going to use oily woods. Specifically, they mentioned cocobolo and kingwood. They basically said the wood will not hold the necessary water and also the adhesive won't penetrate enough to grab well because of the oils. This leads me to think that polyurethanes may be great in some cases, not so great in others, considering the oiliness of so many of the woods we use.

Sounds like it would be awesome for stick tang antler handles if it doesn't exert sufficient pressure to split it during the expansion/cure.

Just a couple thoughts....
Mike, I wonder if that wouldn't be true of any glue on oily woods? I'm guessing no adhesive maker would claim to be able to glue up those woods. I could be wrong. We need a duck call maker to step in here. They work with cocobolo all the time. Gorilla glue has a cool website though.
 
Tracy, that may well be true. I may try a couple experiments myself to aid the cause when I finally start feeling a bit better.

This afternoon I tried a small experiment looking for a residue-free household solvent. I would clean a piece of plate glass as best I could and then put a puddle of solvent on it, let it evaporate, and look for a film. I tried Sunnyside Acetone, Kwik-Klean Denatured alcohol, Osco (drugstore) 70% and 91% isopropyl alcohol, naptha, and JP Industrial Cleaner (a degreasing spray of 1,1,1-trichloroethane. All left noticeable residues. (By the way, I learned that one shouldn't heat plate glass with a heat gun from underneath with solvent on top. It shatters rather explosively! :rolleyes: :D )

For many years, I always "snitched" a bit of whatever solvents I needed from work, always laboratory grade solvents. They were clean but very costly, comparatively.

I am most disappointed by the crap being sold off the shelf.

I am even paranoid with residual detergent being left in clean rags fresh from washing being leached out by the solvents.

I'm of the mind right now that the best way to clean the surfaces prior to "gluing" is to hit it with fresh bonded abrasive to expose fresh surface and use immediately. If I have read correctly, that has produced the best results for you guys, too.

One interesting note I read today suggested that the cyanoacrylates and methacrylates are more tolerant of "dirt" than most other adhesives. That may be something for us to keep in mind.

Is the compressor you used for your blasting oilless or oil? If oil, what kind of cleanup filter do you use?

thanks.
 
Mike, I thought you'd been absent a bit for a reason. Hope you feel better.
I've never added oil to my compressor so it is in fact oiless - I sure don't know if it takes oil or not though. I should look some time.:D
I did not notice any oil from sandblasting. I did notice some moisture that evaporated quickly.

I usually abrade the surface immediately prior to glue up. I rarely clean anything with any solvent and certainly none of these test pieces were solvent cleaned. I counted on the abrasive to do that. I knew acetone leaves an oily residue so I hardly use it and if I do, I follow up with alcohol. The difference between a fresh sharp belt to rough up the surface and a less than new belt I see now as a big deal. I didn't before.

I think a clean, no residue solvent may be searching for the holy grail but there is certainly going to be some better than others. I always use a fresh paper shop towel (Scott) when wiping any surface if I do clean with solvent.
 
Clean, residue-free solvents can be had, but they will have to come from a scientific supply house and will probably be $60/gallon or more.
 
(It's hard to follow everything so I'll repost this with new results.)

OK Report on testbar 3 - The thin glue line test.

To get everything up to date......

This time the bar was ground clean with a 50grit. Then sandblasted with real sand. Wiped off with a paper towel (no solvents).

The attachment method was C-clamping with moderate pressure.

-------------------------------------------------------
After a few days cure:

Impact test (heretoforwards known as "Wack")
Wack
JB Weld - Failed
Wack
Dishwasher
Freeze one hour -
West Systems - Failed
Freeze eight hours
Wack
Wack
Acraglas Gel - Failed
Wack
Boil in water for 15 minutes
Loctite 406 Super Glue - Failed
Wack
Wack
Wack

Still in there:

Loctite Xtreme (some kinda rubberized super glue)
Loctite E-120HP
Loctite U05-FL
Gorilla Glue

Steve
 
I'm finding the same interesting thing as Tracy. This Gorilla glue stuff is alright. The consumer epoxies are all toast. The industrial epoxies are hanging tough.

The only odd ball is that Loctite Xtreme. It's a consumer 'glue'. Single substance. Easy to use. The residual stuff is rubbery. Has not hardened up or discolored after freezing and boiling. And really bonds to metal. It was also the only stuff that bonded over the Simple Green.

Using a 'glue' that doesn't get hard is counter-intuitive. But I can't argue with the results!?

Steve
 
Steve,
A glue that doesn't get hard would allow the contrasting materials' to expand and contract at dissimilar rates and still remain stuck.
Wood that isn't stabilized can grow and shrink quite a bit, depending on species.
Wouldn't a pliable adhesive be the thing to use in that case?
I know the poly glues never get rock hard.
Seen any poly glues that cured clear? I haven't.
 
Howie,

That flexible attribute is really a plus in my book.

My current test is the "Thin Glue Line". There's not visible glue line on any of these remaining samples. But just soo's you know's the colors

Xtreme is translucent - pretty darned clear
U-05fl is a 2-part Urethane adhesive - white/translucent
E-120HP is whitish (color of acraglas gel)
Gorilla Glue is tan

However, non of these have a visible line. So color ain't much of an issue.
---------------------------------------
The test bar spent the night in the oven at low temp. Everything's fine. Again I thought the Xtreme would break down. Even when hot the excess was rubbery and the block is held firm.

----------------------------------------

FWIW: I'm now leaning towards U-05FL as the ultimate adhesive. (But if Xtreme holds up.....) Remains somewhat flexible and yet adhesion is superior to all the 'regulars', easy to apply. It expands so it needs a strong clamp, but so what. The one time I used it on a knife I had to go back an hour later to clean of some stuff where it expanded over something I didn't want to. It was rubbery still and scraped off easily with a piece of wood. No residue to clean up. Very nice.

Compare that with the polyurethanes that expand, really hard to clean off and don't stick to some materials. Or the most of the epoxies that are not impact,temperature resistant.

--------------------------------------------------
Currently my test bar is getting frozen into a block of ice.

---------------------------------------------------------
Steve
 
(in another thread far away Steve asked about the 324 Loctite Speedbonder adhesive)

Steve, the 324 is a bit different. First you spray the surfaces with a fixative and wait for a few minutes for the solvent to evaporate. Then apply a drop or two - because it is so ungodlyfricking expensive and clamp. The contact surfaces that are clamped cure to 'fixture' cure (what ever that is) in 4 minutes or so. Loctite is vague about the final cure strenght but I gave it 24 hours. Any edges that the adhesive oozed out of the pieces being glued, stayed sticky and did not cure even if was on a surface that was sprayed. It's very odd behavior that I'm not sure I'm comfortable with yet. In each of my two load tests however, the joint was fine.

I did a couple more load tests tonight, sorry no pics, on gorilla glue metal to metal, metal to liner to metal and then also shafting epoxy metal to metal.

First, the gorilla glue metal to metal failed immediately. It never set up properly. This stuff takes moisture to kick off and even when I when wet the pieces and put water in the joint to get it going. It failed to take any kind of grip at all. Gorilla glue should definately NOT be used for metal to metal adhesion. The metal to liner to metal piece held 50lbs and then the glue joint failed. I had expected the liner material to fail before the glue. I thought this was interesting and frankly a failure at 50lbs was surprising. I thought if the liner material held, it would go 75lbs at least. I'm going to try a wood piece sandwich and see what that does.

On a side note, there has been a few comments about the excess foam around some of the test pieces giving it a mechanical lock and unfair advantage. This foam excess stuff has almost no strength at all and can be scrapped away with your finger nail. The gorilla web site has some good information on this glue at www.gorillaglue.com This glue has no strength for gap filling at all so if it foams up in a gap, that foam has no strength which is not what you would guess by looking at it work. Foam bad.

The golf shafting epoxy failed cleanly at 50lbs. I'm OK with that I guess. I'd like to have seen more but this is a very strenuous test and a 1" square glue joint holding 50lbs leveraged by 4" is still pretty good. Golf bad. (oops that slipped)

Sooo, the hands down winner on my kinda shear/tensile/load test is the 324 Loctite Speedbonder followed by PC-7.
 
The 324 may be what is called an "anaerobic" adhesive. Those won't cure in the presence of air, apparently, from what I read the other day. A comment was made about the quality of curing at the exposed edges not being as good as in the center, because of air exposure impeding full strength.

I'm not sure this is applicable to this adhesive, but I thought I'd mention the possibility.

Thanks for the info on the Gorilla Glue and strength of the foam, Tracy. That pretty much eliminates it for use in a hidden tang knife, IMO.

Great info this study is providing!!!
 
Tracy,

OK the commercial 'glues' are winning. (Like that should be news.)

I'd like to compare 324 and E-120HP. Running the same tests. Apart from that, I'll compare the data sheets:

E-120HP - Shear strength on Steel = 4270
324 - Shear strength on steel 3000 +/- 500


E-120HP - at 122f is at full strength. At 212f it's at 50% strength.
324 - at 122f is at 60% strength. At 212f is at 12% strengh

(This stat doesn't mean much cause our stuff isn't exposed, but...)
E-120HP - soaked in water/glycol for 1000 hours - 89%
324 - soaked in water/glycol for 720 hours - 50%

324 - strongest at 0 thickness
120HP - strongest at .003"

As all ready proven both these adhesives are awsome! So I suppose it comes down to price/ease of use.

With 324 I really like the part about being able to remove the glue after everything is dry. That's pretty neat.

Maybe I should send you my 120HP for a side by side.

Steve

PS Here's a link someone found on a lab test with 120HP:

http://dot.etec.wwu.edu/fsae/v35/Safety/index.htm
 
Steve where did you get that strength/temp data? I've been all over the loctite site and didn't find that. It's not in their PDF file or have I overlooked it?

If 324 is in fact only 12% strength a boiling is that a problem?

Time for some input:
What would be the highest temp a knife would be exposed to under the harshest of user conditions? I'd guess 180F might be the hottest a knife would get in any real world military situation. It would be too hot to hold at that temp but could get to that temp in the sun in a closed vehicle in the desert.
 
fitzo said:
The 324 may be what is called an "anaerobic" adhesive. Those won't cure in the presence of air, apparently, from what I read the other day. A comment was made about the quality of curing at the exposed edges not being as good as in the center, because of air exposure impeding full strength.
I'm not sure this is applicable to this adhesive, but I thought I'd mention the possibility.
Thanks for the info on the Gorilla Glue and strength of the foam, Tracy. That pretty much eliminates it for use in a hidden tang knife, IMO.
Great info this study is providing!!!
Mike, the 324 speedbonder is in fact anaerobic as I just read in the technical data sheet. I am concerned about a couple things with this adhesive. The fact that is is anaerobic and the targeted use is wood scales that will normally overlap the tang exposing the edge to air and not being cured. The second issue is the 12% strength at boiling point. I'm going to start boiling tests on a few pieces but this has me concerned about what initially was a very exciting candidate. I now have at least a slight bias against this stuff. I have not done many tests on it so it's too early to kill it but it sure is wounded.
 
Tracy,

One thing to remember, these crazy 'glues' get weak when not, but return to normal when they cool back to room temp. On the Loctite sheets you'll notice that 324 loses strength at 100c. However, if it stays at 120c for 1000 hours and retested at 22c it's actually stronger.

I don't know if that makes a difference to you, but it's interesting.
Steve

Steve
 
some time ago when Steve Sando and I started testing adhesives, we started a few threads on it. I promised I would come back with some results and conclusions after it became too much to maintain all the threads. Here are the results I came up with, Steve is AWOL as he is a busy guy lately, so his results will follow but they are close to these I'm fairly sure. At the end of this is a link to an Excell spreadsheet with some additional data. I'd invite any comments if any one has any.


I learned several things from these adhesive experiments.

First, I had been told over several years by very good knife makers, that Devcon 2 ton epoxy was a great choice for knife making. They had been told, no doubt by other great knife makers that it was great adhesive. Devcon 2 part epoxy was one of the very first adhesives to fail both Steve’s tests and mine. It rarely lasted more than a few cycles through the dishwasher. The learning here was: test and check every thing you’ve been told even if it comes from a very good source. Nothing beats an opinion more than testing it yourself. Given this, you probably shouldn’t believe another word that follows this one. I know I don’t believe half of what comes out of my mouth some times.

The second learning:
Surface preparation is more important to a successful glue up than is the adhesive its self. Please don’t underestimate surface preparation. A mediocre adhesive with an excellent surface preparation will out perform an excellent adhesive with a poor preparation by a large margin.
Steve diligently cleaned some of his test pieces with Simple Green, a soap that is often recommended for cleaning all kinds of things. The simple green apparently left a residue that prematurely failed all of his initial adhesive tests. Other surface cleaning solutions also left a residue that impaired adhesive performance.
My tests on a roughed up or scratched surface using a fresh 36 grit belt versus sand blasting gave exceptionally clear results. On ten test pieces I prepared, one end was sand blasted and the other scratched with a 36 grit belt, all of the scratched surfaces failed. Six of ten of the sandblasted surfaces survived. THIS IS HUGE. Again, routinely, high caliber and very competent knife makers recommended scratching or roughing up the surface of a knife to provide a better purchase for the adhesive. Certainly this is true but sandblasting a surface vastly out performs a scratched surface to the point where I recommend a knife maker absolutely invest in at least a minimal sandblasting setup to prepare a surface for glue up. Watch chemical cleaners for residue. Test this by allowing you cleaning chemical to dry on a piece of glass and have a look. I use isopropyl alcohol myself.

Third learning:
Read up on your adhesive. With the Internet, there really isn’t a reason you can’t completely understand what you are working with. Gorilla glue was being used or at least considered for use in full tang knives since it tended to expand as it cured. I thought this was a great feature of this particular adhesive. It also seemed to make this adhesive perfect use for a full tang knife. Fill the hollow in the handle material part way, put it together and let the expansion fill the rest of the hollow. The problem is that the expanded (foam looking) adhesive has no mechanical strength at all. This was documented fairly clearly on the Gorilla glue web site but had not been ‘reported’ to others on the forums as a caution. On the other hand, you can’t believe every thing you read. JB Weld failed most dishwasher tests and is reportedly good up to over 400 degrees Fahrenheit. They must mean a dry heat dishwasher.

Fourth learning:
There is no one perfect adhesive. There are some that work really, really well at some things but not at all things. Gorilla glue outperformed every adhesive in my destructive tests when gluing wood to metal. It failed miserably when gluing metal to metal or metal to Micarta. Loctite Speedbonder 324 held a stunning 100lbs of weight when bonding metal to metal but failed early gluing metal to wood.

Fifth learning:
Thicker glue is easier to use than thin glue. Viscosity ratings are impossible to relate to so I’d suggest the perfect viscosity is butterscotch pudding. Peanut butter consistency is too thick, syrup is to runny and messy. This makes such a difference that if a couple of adhesives are close in performance, the hands down choice would be to go with the butterscotch stuff. I hope I’m not being too technical.

Sixth learning:
There are some amazing adhesives out there. Amazing adhesives. Our recommendations can and probably should fall to the wayside over the next several years as adhesives technology continues to improve. They glue cars together now instead of welding or rivets. Cars!
Glued together! What the hell? Keep an eye open for new adhesives but make sure and test it.

Seventh learning:
Testing wasn’t all that hard. If you find a new adhesive you want to test, glue some wood to metal and throw it in the dishwasher for a half a dozen cycles. If it survives that, you might have something. If it doesn’t, don’t even consider it. If it makes it through the dishwasher tests, boil it for an hour or so. If it makes it past that test, you are really on to something. From there make something else up and let us know what you’ve found as you are probably on to a good one.

Eighth learning:
Industrial adhesives are generally better than adhesives packaged for retail sales to the general public. There are exceptions of course but it generally holds true. K&G epoxy, which is a recommended adhesive from our tests, is industrial epoxy ‘repackaged’ and marketed to knife makers and gunsmiths.

Ninth learning:
Gorilla glue shouldn’t have held up like it did. It was supposed to fail early and was just meant to bulk up the tests. It kicked most every other adhesives ass all over the block. Keep an eye out for things that aren’t supposed to work and try them out.

Tenth learning:
Steve found some adhesives I never would have. I found some he didn’t. Collaboration and sharing information helps the process. Not really a new learning but it’s worth repeating and it was clearly demonstrated here.

Eleventh learning:
There is a type of adhesive that cures by a lack of oxygen. I’d never heard of anything like it before. It’s called anaerobic curing adhesive and won’t cure well when the material is porous like wood.

AND NOW FINALLY….


For wood handle scales to metal:
Recommended:
Gorilla Glue beat out every other adhesive in every test
Loctite E-120hp
K&G epoxy
Golf shafting epoxy by Golfsmith
Acraglass

Avoid:
Anaerobic curing adhesives
JB Weld

Full tang handles:
Acraglass which was designed almost exactly for this kind of application.

Avoid:
Gorilla Glue or any other polyurethane expanding type glue.

For metal to metal
Recommended:
Loctite Speedbonder 324
JB Weld
PC7

Avoid:
Any CA’s, ie superglues. These have no place in knife making anywhere except to fill flaws in handle material.

For metal to man made materials (ie, G10, micarta, etc)
Recommended:
Loctite 324 Speedbonder or any of the overall use adhesives.

For overall use:
Loctite E-120hp
K&G Epoxy
Golfsmith Golf shafting epoxy
Acraglass (Acraweld is different and was not tested. Acragel was tested and failed)

adhesive spreadsheet
 
Tracy,

Thanks for all the hard work. This thread has been very imformative to a newbie like me. I feel better knowing that the Gorilla Glue and K&G epoxy I bought by chance should serve me well, for now at least.

Great work!
 
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