Glue Wars 2

this thread keeps just popping back up. shows how useful it is ;)

Has anybody used or compared methacrylates rather than epoxies?

I've been looking around and some people elsewhere have suggested methacrylate but nobody seems to have tested them. Thought they may be an alternative to epoxy? If we need such a thing?

I'm particularly looking for something with gap filling properties and for use with natural materials. I've been using an industrial Araldite epoxy (2011) up til now, but I'm finding that it abosrbs moisture like the wood. So it doesn't crack off (which is good) but when teh wood recedes again teh glue doesn't always follow (not sure how this will play out long term?). I've not had any customers complain, but my own users are showing these things and I don't think I like it.
 
My father-in-law builds custom golf clubs, and recently gave me a couple adhesives to try on knives. One is Epibond 1217, which is a methylacrylate. He said the custom club builders are using it more and more over the Golfsmith 2-part system because it has a higher shear strength and it etches the metal to form a stronger bond.

I haven't tried it yet, but I will in the upcoming months.
 
ok i looked and i swear i could not find my answer. has anyone tried gorilla epoxy? i know the glue faired well, im wondering how the epoxy would do--marekz
 
Hell, might as well throw this one into the mix---yes, I know, it's a horribly specific mixture (3.1:1 I believe) and is only available in large quantities so probably nobody has used it, but GAWD look at those properties!!!!!!

Devcon Titanium Putty
 
One is Epibond 1217, which is a methylacrylate. He said the custom club builders are using it more and more over the Golfsmith 2-part system because it has a higher shear strength and it etches the metal to form a stronger bond.


That sounds promising! I wonder how many other adhesives out there can claim that they etch the metal during the bonding process? Guess another question is what is the cure rate? Found it... 1 to 2 hours at 77deg
 
some time ago when Steve Sando and I started testing adhesives, we started a few threads on it. I promised I would come back with some results and conclusions after it became too much to maintain all the threads. Here are the results I came up with, Steve is AWOL as he is a busy guy lately, so his results will follow but they are close to these I'm fairly sure. At the end of this is a link to an Excell spreadsheet with some additional data. I'd invite any comments if any one has any.


I learned several things from these adhesive experiments.

First, I had been told over several years by very good knife makers, that Devcon 2 ton epoxy was a great choice for knife making. They had been told, no doubt by other great knife makers that it was great adhesive. Devcon 2 part epoxy was one of the very first adhesives to fail both Steve’s tests and mine. It rarely lasted more than a few cycles through the dishwasher. The learning here was: test and check every thing you’ve been told even if it comes from a very good source. Nothing beats an opinion more than testing it yourself. Given this, you probably shouldn’t believe another word that follows this one. I know I don’t believe half of what comes out of my mouth some times.

The second learning:
Surface preparation is more important to a successful glue up than is the adhesive its self. Please don’t underestimate surface preparation. A mediocre adhesive with an excellent surface preparation will out perform an excellent adhesive with a poor preparation by a large margin.
Steve diligently cleaned some of his test pieces with Simple Green, a soap that is often recommended for cleaning all kinds of things. The simple green apparently left a residue that prematurely failed all of his initial adhesive tests. Other surface cleaning solutions also left a residue that impaired adhesive performance.
My tests on a roughed up or scratched surface using a fresh 36 grit belt versus sand blasting gave exceptionally clear results. On ten test pieces I prepared, one end was sand blasted and the other scratched with a 36 grit belt, all of the scratched surfaces failed. Six of ten of the sandblasted surfaces survived. THIS IS HUGE. Again, routinely, high caliber and very competent knife makers recommended scratching or roughing up the surface of a knife to provide a better purchase for the adhesive. Certainly this is true but sandblasting a surface vastly out performs a scratched surface to the point where I recommend a knife maker absolutely invest in at least a minimal sandblasting setup to prepare a surface for glue up. Watch chemical cleaners for residue. Test this by allowing you cleaning chemical to dry on a piece of glass and have a look. I use isopropyl alcohol myself.

Third learning:
Read up on your adhesive. With the Internet, there really isn’t a reason you can’t completely understand what you are working with. Gorilla glue was being used or at least considered for use in full tang knives since it tended to expand as it cured. I thought this was a great feature of this particular adhesive. It also seemed to make this adhesive perfect use for a full tang knife. Fill the hollow in the handle material part way, put it together and let the expansion fill the rest of the hollow. The problem is that the expanded (foam looking) adhesive has no mechanical strength at all. This was documented fairly clearly on the Gorilla glue web site but had not been ‘reported’ to others on the forums as a caution. On the other hand, you can’t believe every thing you read. JB Weld failed most dishwasher tests and is reportedly good up to over 400 degrees Fahrenheit. They must mean a dry heat dishwasher.

Fourth learning:
There is no one perfect adhesive. There are some that work really, really well at some things but not at all things. Gorilla glue outperformed every adhesive in my destructive tests when gluing wood to metal. It failed miserably when gluing metal to metal or metal to Micarta. Loctite Speedbonder 324 held a stunning 100lbs of weight when bonding metal to metal but failed early gluing metal to wood.

Fifth learning:
Thicker glue is easier to use than thin glue. Viscosity ratings are impossible to relate to so I’d suggest the perfect viscosity is butterscotch pudding. Peanut butter consistency is too thick, syrup is to runny and messy. This makes such a difference that if a couple of adhesives are close in performance, the hands down choice would be to go with the butterscotch stuff. I hope I’m not being too technical.

Sixth learning:
There are some amazing adhesives out there. Amazing adhesives. Our recommendations can and probably should fall to the wayside over the next several years as adhesives technology continues to improve. They glue cars together now instead of welding or rivets. Cars!
Glued together! What the hell? Keep an eye open for new adhesives but make sure and test it.

Seventh learning:
Testing wasn’t all that hard. If you find a new adhesive you want to test, glue some wood to metal and throw it in the dishwasher for a half a dozen cycles. If it survives that, you might have something. If it doesn’t, don’t even consider it. If it makes it through the dishwasher tests, boil it for an hour or so. If it makes it past that test, you are really on to something. From there make something else up and let us know what you’ve found as you are probably on to a good one.

Eighth learning:
Industrial adhesives are generally better than adhesives packaged for retail sales to the general public. There are exceptions of course but it generally holds true. K&G epoxy, which is a recommended adhesive from our tests, is industrial epoxy ‘repackaged’ and marketed to knife makers and gunsmiths.

Ninth learning:
Gorilla glue shouldn’t have held up like it did. It was supposed to fail early and was just meant to bulk up the tests. It kicked most every other adhesives ass all over the block. Keep an eye out for things that aren’t supposed to work and try them out.

Tenth learning:
Steve found some adhesives I never would have. I found some he didn’t. Collaboration and sharing information helps the process. Not really a new learning but it’s worth repeating and it was clearly demonstrated here.

Eleventh learning:
There is a type of adhesive that cures by a lack of oxygen. I’d never heard of anything like it before. It’s called anaerobic curing adhesive and won’t cure well when the material is porous like wood.

AND NOW FINALLY….


For wood handle scales to metal:
Recommended:
Gorilla Glue beat out every other adhesive in every test
Loctite E-120hp
K&G epoxy
Golf shafting epoxy by Golfsmith
Acraglass

Avoid:
Anaerobic curing adhesives
JB Weld

Full tang handles:
Acraglass which was designed almost exactly for this kind of application.

Avoid:
Gorilla Glue or any other polyurethane expanding type glue.

For metal to metal
Recommended:
Loctite Speedbonder 324
JB Weld
PC7

Avoid:
Any CA’s, ie superglues. These have no place in knife making anywhere except to fill flaws in handle material.

For metal to man made materials (ie, G10, micarta, etc)
Recommended:
Loctite 324 Speedbonder or any of the overall use adhesives.

For overall use:
Loctite E-120hp
K&G Epoxy
Golfsmith Golf shafting epoxy
Acraglass (Acraweld is different and was not tested. Acragel was tested and failed)

adhesive spreadsheet

i was browsing the internet looking for knife making info and found this thread about glue strength and found this very intereting. About the comment of glueing cars together though is only partly true. Even though some parts of some cars are glued welding is still king, but it is actually nessasary on automobiles such as the oldsmobile silhouete van, this has a body that is glued to an internal structural frame, many other cars also have a similar setup. In any case where there are glued panels thy are non structrual. Some examples of these are LORD Fusor and 3M duramix. These are avalible to glue metal to metal, metal to plastic and plastic to plastic. Sadly though these are not avalibe to bond wood. The strength of these products is almost insane. My dad did a test one time and the metal tore before the glue broke. These are two part epoxies that are extremely strong and very popular for patch panels and bonding nonstructural replacement panels. If you wanted to use them expect to have to order them from a company that speciaizes in automovive repair suplies. These are not avalibe at an auto parts store or home center. Search 3M duramix or lord Fusor on www.autobodytoolmart.com to find them.
 
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I work at a major corporation as an Engineering Supervisor for Research and Development. We are currently performing testing on adhesives to bond steel to steel. I hope to provide a summary of our findings once the tests have been completed, probably in about 2 weeks.

Mike L.
 
I work at a major corporation as an Engineering Supervisor for Research and Development. We are currently performing testing on adhesives to bond steel to steel. I hope to provide a summary of our findings once the tests have been completed, probably in about 2 weeks.

Mike L.


I sure would like to see that when you get it.
 
Was looking at glue in home depot today, and I see that they're selling "extreme repair adhesive" under the LePage label up here in the Great Northern Tundra. Haven't tried it yet, but Henkel owns both brands so I'm assuming it's the same as the Loctite stuff.

Haven't found a good source for E-120HP yet. I'm starting to think it's all a trick to get me to order some speedbonder from Tracy...
 
very nice. very thorough.
although there is one other I finde is quite strong. if you mix gorilla glue, and liquid nails (or something else as long as it works ok) you end up with a little bit of foaming, which can be nice if you have large gaps, but the bubles are much much smaller and stronger.
Is good:thumbup:
 
Was looking at glue in home depot today, and I see that they're selling "extreme repair adhesive" under the LePage label up here in the Great Northern Tundra. Haven't tried it yet, but Henkel owns both brands so I'm assuming it's the same as the Loctite stuff.

Haven't found a good source for E-120HP yet. I'm starting to think it's all a trick to get me to order some speedbonder from Tracy...


that made me laugh. I'd have to have a pretty good foresight. I did those test 2 years before I got into the supply thing...:D
 
wow bi found your thread and testing to be ... well ... impressively wow
any up dates?
 
Tracy after a glue failed did you reapply it to the test board to undergo the rest of the tests?

Im wondering if some hold up better to cold than others, or if others fail in heat more so.
 
Almost all of them have operating temperatures listed on their packaging.
 
I have used Lord adhivses metal to metal and it is stronger then 1/16 alum on a pull test that wose done at the shop i work at. This is some strong glue and lord makes all kinds of glue so maby someone can look that has more experiance at there glue. JRH
 
I sure would like to see that when you get it.

For steel to steel, where shear strength is the concern with a modest gap of about .01" per side . . . the metal epoxies will meet or beat the other adhesives. We were testing for shear strength of metal sleeve bonded to a metal pipe. Not directly related to knife scales bonded to tangs, but of interest when considering generous gaps.

Of course, surface prep and cleanliness is an important variable too.

Mike L.
 
I wonder if anyone has thought to revisit these tests with the epoxies available today? I don't have the patience nor the organizational skills for it but I would really be interested in what people are using these days. I jsut bought some loctite 2 part epoxy in a syringe to put scales on a full tang knife and now I'm questioning whether I should use something else.
 
Question about the epoxies: Does it matter how thick the layer is? Does it do better if you clamp tight and the layer is very thin or if you clamp loose and a thick layer of epoxy remains?

This bums me out as I recenty bought the large tubes of devcon 2 ton epoxy. I have used it on a few knife handles and I think I have had it fail in certain circumstances but I don't remmeber exactly.
I did have a spoon kit where I used some dyed stabilized burl wood and the wood is peeling away from the metal. This may be in part a failure of the wood as well though since I see that the wood seems to be expanding, probably from sitting in water.

So would it be the general concensus that 2 ton epoxy should not be used on knives anymore? Part of my problems in the past may have been surface prep. I would rough up the surface a little bit and use paint thinner to wipe it down. I have heard acetone is the best to use since it leaves no residue so I bought that to clean off oils and dust. I am wondering how many of my difficulties were from some film that whatever paint thinner type material i used was leaving behind. EDIT: When i read page 2 here I saw that almost every cleaner left some sort of residue... I guess I will try the glass test and see how that turns out. Not sure what to use, just sand by itself and hope the dust brushes off witha cloth or something?

When I have tried to remove handles sometimes I have had it come off very cleanly from one of the materials, usually the metal if i remeber correctly.

I checked my local hardware store today but I didn't see the one that was recomended, the acraglass. Anyone know where to get this one is it specail or something?

My dad didn't really like the gorilla glue for some reason so i think i got a bottle. Ill have to start using it when doing wood. I know I had had trouble working with it before. I don't know if I knew about the moisture prep though.
 
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The second learning:
Surface preparation is more important to a successful glue up than is the adhesive its self. Please don’t underestimate surface preparation. A mediocre adhesive with an excellent surface preparation will out perform an excellent adhesive with a poor preparation by a large margin.
Steve diligently cleaned some of his test pieces with Simple Green, a soap that is often recommended for cleaning all kinds of things. The simple green apparently left a residue that prematurely failed all of his initial adhesive tests. Other surface cleaning solutions also left a residue that impaired adhesive performance.
My tests on a roughed up or scratched surface using a fresh 36 grit belt versus sand blasting gave exceptionally clear results. On ten test pieces I prepared, one end was sand blasted and the other scratched with a 36 grit belt, all of the scratched surfaces failed. Six of ten of the sandblasted surfaces survived. THIS IS HUGE. Again, routinely, high caliber and very competent knife makers recommended scratching or roughing up the surface of a knife to provide a better purchase for the adhesive. Certainly this is true but sandblasting a surface vastly out performs a scratched surface to the point where I recommend a knife maker absolutely invest in at least a minimal sandblasting setup to prepare a surface for glue up. Watch chemical cleaners for residue. Test this by allowing you cleaning chemical to dry on a piece of glass and have a look. I use isopropyl alcohol myself.

This leaves me at a dilema. I am not able to invest in a sand blaster but I want good results. I wonder if a random orbit sander would be a good prep since it really hits everything rather than just carving channels in the metal as would some 36 grit going back and forth...
So what do you recomend to remove the dust and the oils from hands before glueing? I realize sanding would remove some of the oils but then you have metal dust as a problem.
 
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