Cliff Stamp
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- Oct 5, 1998
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What upper temperatures are you talking about?
Secondary hardening.
Carbide precipitation does not cause transformation of austenite to martensite.
When the alloy precipitates out of the austenite it conditions it and thus martensite will form in the cooling after the temper, this doesn't happen at lower temperatures. At lower temperatures you can get other phases such as bainite depending on the TTT curves, you would not expect it in S30V though as it is air hardening. You can also get pearlite in the upper temperatures but not for air hardening steels, that would be more for spring tempering an oil/water steel.
Double or triple tempering is advisable for air-hardening, hot-work, and high speed steel tools.
Yes as these are commonly all tempered very hot as I noted, you don't get the same phase transformations with low tempers. If for example you took M2 and tempered it low, even a bunch of times, you would not transform the austensite by inducing martensite to form. You can't even minimize retained austenite with cold treatment which Landes noted which surprised me. The really high alloy steels require the conditioning of the high tempers because the austenite stabilizes extremely rapidly.
It would be a shame to have it disappear from the market, because the issues with it do not get solved and that because we fight a war over false claims that someone made somewhere about the steel.
It is simply noting that many of the reasons given to explain the performance are contradictory with the known properties of P/M's and the way the steel is currently promoted. What would be a shame is to not be very skeptical of any claims made to explain a problem because unless they are supported under critical examination the problem will persist because obviously the real issue was not determined.
From what I have read, my impression was that the differences between a piece that is allowed to cool slowly and one that is quenched/cooled with plates, is FAR greater, but my sources are only snippets off the internet.
What sources, actual materials references or just makers selling the steel? There is a wealth of materials data on the effects of air vs oil on air hardening steels, this isn't an issues specific to a couple of CPM steels. They are of course used in industry with just air hardening as that is how they were designed. You can also just ask the manufacturers directly (look at the published data) you can expect a small increase in the hardness, 1-2 points, and small effects on corrosion resistance/toughness, with the latter being also effected by the lower hardness. Landes has studied this in detail as well which is why he does water quenching after tempering so you can discuss it with him and he will be very specific about what it does. However if you don't water quench after tempering it doesn't mean the steel is ruined, again, this is a small refinement.
It is just that I have read on multiple forums by multiple people that they had problems with S30V and 3V before they employed cooling plates or other means of quickly pulling of heat.
Note the problem with S30V is generally it is too brittle, air hardening would not have this effect in general because it softens the steel. The main problems are not with rolling but chipping, though some like Sodak have noted poor edge retention due to softness which was corrected by Wilson with a rehardening. There have been some issues with 3V and deformation such as Ralph noted when he used the steel but I would be skeptical that it was a hardness issue and he never realized it and again this is an air hardening steel. Note Carpenter makes a very similar steel so you can just ask them about it. I have had a few exchanges with them about their P/M's. Knives are actually very slim cross sections and thus they cool relatively quickly due to a high area/volume ratio. Generally the main use of aggressive quenches on air hardening steels is for very large parts which such a heat capacity that they can hold onto the heat long enough to hit the pearlite section of the TTT curve.
You might also want to email Krauss who is by any defination an expert on steels and ask him about the effect of air vs oil on steels with a highly displaced pearlite nose. You could also just read his ASM reference books, which in general are invaluable references. Any decent library will have them, or will just get them on loan. He also has new editions out which I plan to buy shortly. I think I'll do a pass around if there is interest, maybe create some kind of mini-reference library.
-Cliff